Doeville is an unincorporated community in Johnson County, Tennessee, United States. It is concentrated around the intersection of Tennessee State Route 67 and Tennessee State Route 167, west of Mountain City and east of Butler. The community of Pandora lies immediately to the northeast along S.R. 67.Doeville is situated in the lower Doe Creek Valley, near the stream's confluence with Roan Creek at the headwaters of Watauga Lake.