Ware County is a county located in the southeast of the U.S. state of Georgia. As of the 2010 census, the population was 36,312. The county seat is Waycross.Ware County is part of the Waycross, GA Micropolitan Statistical Area.By geographic area, Ware County is the largest Georgia county. There's a local saying that the county seat of Waycross is "the largest city in the largest county in the largest state, east of the Mississippi".